8.09.2010
8.05.2010
H2O
Water is one of most precious liquid, solid or gas that exist in our Universe. Can be liquid, solid like ice or gas. Many believe that water is very important for exist life on Earth or in the Universe.
Water (H2O) is the most abundant compound on Earth's surface, constituting about 70% of the planet's surface.
It is in dynamic equilibrium between the liquid and gas states at standard temperature and pressure. At room temperature, it is a nearly colorless with a hint of blue, tasteless, and odorless liquid. Many substances dissolve in water and it is commonly referred to as the universal solvent. Because of this, water in nature and in use is rarely pure and some of its properties may vary slightly from those of the pure substance. However, there are many compounds that are essentially, if not completely, insoluble in water. Water is the only common substance found naturally in all three common states of matter and it is essential for life on Earth. Water usually makes up 55% to 78% of the human body.
The liquid phase is the most common among water's phases and is the form that's generally denoted by the word "water." The solid phase of water is known as ice and commonly takes the structure of hard, amalgamated crystals, such as ice cubes, or loosely accumulated granular crystals, like snow. For a list of the many different crystalline and amorphous forms of solid H2O. The gaseous phase of water is known as water vapor (or steam), and is characterized by water assuming the configuration of a transparent cloud. The fourth state of water, that of a supercritical fluid, is much less common than the other three and only rarely occurs in nature. When water achieves a specific critical temperature and a specific critical pressure (647 K and 22.064 MPa), liquid and gas phase merge to one homogeneous fluid phase, with properties of both gas and liquid. Since water only becomes supercritical under extreme temperatures or pressures, it almost never occurs naturally.
Water is the chemical substance with chemical formula H2O: one molecule of water has two hydrogen atoms covalently bonded to a single oxygen atom. Water is a tasteless, odorless liquid at ambient temperature and pressure, and appears colorless in small quantities, although it has its own intrinsic very light blue hue. Ice also appears colorless, and water vapor is essentially invisible as a gas.
Water is primarily a liquid under standard conditions, which is not predicted from its relationship to other analogous hydrides of the oxygen family in the periodic table, which are gases such as hydrogen sulfide. Also the elements surrounding oxygen in the periodic table, nitrogen, fluorine, phosphorus, sulfur and chlorine, all combine with hydrogen to produce gases under standard conditions. The reason that water forms a liquid is that oxygen is more electronegative than all of these elements with the exception of fluorine. Oxygen attracts electrons much more strongly than hydrogen, resulting in a net positive charge on the hydrogen atoms, and a net negative charge on the oxygen atom. The presence of a charge on each of these atoms gives each water molecule a net dipole moment. Electrical attraction between water molecules due to this dipole pulls individual molecules closer together, making it more difficult to separate the molecules and therefore raising the boiling point. This attraction is known as hydrogen bonding. The molecules of water are constantly moving in relation to each other, and the hydrogen bonds are continually breaking and reforming at timescales faster than 200 femtoseconds.
For existing life on Earth many creatures depend of water and without this precious elements, Earth probably was a giant desert. Exist many teories how water appears in past in our planet, the common, are that water came with comets and asteroids in the started of our planet formation.
7.23.2010
Stars
In Universe exist many stars, trillions of stars and many types of stars. Not all stars are like our sun. Some stars are more bigger than the sun, other more small than the sun.
The spectral class of a star is a designated class of a star describing the ionization of its chromosphere, what atomic excitations are most prominent in the light, giving an objective measure of the temperature in this chromosphere. Light from the star is analyzed by splitting it up by a diffraction grating, subdividing the incoming photons into a spectrum exhibiting a rainbow of colors interspersed by absorption lines, each line indicating a certain ion of a certain chemical element. The presence of a certain chemical element in such an absorption spectrum primarily indicates that the temperature conditions are suitable for a certain excitation of this element. If the star temperature have been determined by a majority of absorption lines, unusual absences or strengths of lines for a certain element may indicate an unusual chemical composition of the chromosphere.
Stars are currently classified using the letters O, B, A, F, G, K and M, where O stars are the hottest and the letter sequence indicates successively cooler stars up to the coolest M class. According to an informal tradition, O stars are "blue", B "blue-white", A stars "white", F stars "yellow-white", G stars "yellow", K stars "orange", and M stars "red".
the current star classification system, the Morgan-Keenan system, the spectrum letter is enhanced by a number from 0 to 9 indicating tenths of the range between two star classes. Another dimension that is included in the Morgan-Keenan system is the luminosity class expressed by the Roman numbers I, II, III, IV and V, expressing the width of certain absorption lines in the star's spectrum. It has been shown that this feature is a general measure of the size of the star, and thus of the total luminosity output from the star. Class I are generally called supergiants, class III simply giants and class V either dwarfs or more properly main sequence stars.
Class O stars are very hot and very luminous, being bluish in color; in fact, most of their output is in the ultraviolet range. These are the rarest of all main sequence stars. About 1 in 3,000,000 of the main sequence stars in the solar neighborhood are Class O stars.
Class B stars are extremely luminous and blue. Their spectra have neutral helium, which are most prominent at the B2 subclass, and moderate hydrogen lines. Ionized metal lines include Mg II and Si II.
Class A stars are amongst the more common naked eye stars, and are white or bluish-white. They have strong hydrogen lines, at a maximum by A0, and also lines of ionized metals (Fe II, Mg II, Si II) at a maximum at A5.
Class F stars have strengthening H and K lines of Ca II. Neutral metals (Fe I, Cr I) beginning to gain on ionized metal lines by late F. Their spectra are characterized by the weaker hydrogen lines and ionized metals. Their color is white.
Class G stars are probably the best known, if only for the reason that our Sun is of this class. About 1 in 13 of the main sequence stars in the solar neighborhood are Class G stars.
Class K are orangish stars which are slightly cooler than our Sun. Some K stars are giants and supergiants, such as Arcturus, while orange dwarfs, like Alpha Centauri B, are main sequence stars. They have extremely weak hydrogen lines, if they are present at all, and mostly neutral metals (Mn I, Fe I, Si I). By late K, molecular bands of titanium oxide become present. About 1 in 8 of the main sequence stars in the solar neighborhood are Class K stars. There is a suggestion that K Spectrum stars are very well suited for life.
Class M is by far the most common class. About 76% of the main sequence stars in the solar neighborhood are Class M stars. Although most Class M stars are red dwarfs, the class also hosts most giants and some supergiants such as Antares and Betelgeuse, as well as Mira variables. The late-M group holds hotter brown dwarfs that are above the L spectrum.
Our sun for example, has the spectral type G2V ('yellow' two tenths towards 'orange' main sequence star).
7.20.2010
Lithium
Lithium, the symbol Li (number atomic 3), is a soft, silver-white metal that belongs to the alkali metal group of chemical elements. Under standard conditions it is the lightest metal and the least dense solid element.
According to modern cosmological theory, both stable isotopes of lithium—6Li and 7Li—were among the 3 elements synthesized in the Big Bang. Though the amount of lithium generated in Big Bang nucleosynthesis is dependent upon the number of photons per baryon, for accepted values the lithium abundance can be calculated, in the universe: older stars seem to have less lithium than they should, and some younger stars have far more. The lack of lithium in older stars is apparently caused by the "mixing" of lithium into the interior of stars, where it is destroyed.
Furthermore, lithium is produced in younger stars. Though it transmutes into two atoms of helium due to collision with a proton at temperatures above 2.4 million degrees Celsius (most stars easily attain this temperature in their interiors), lithium is more abundant than predicted in later-generation stars, for causes not yet completely understood.
Though it was one of the 3 first elements to be synthesized in the Big Bang, lithium, as well as beryllium and boron are markedly less abundant than the elements with either lower or higher atomic number. This is due to the low temperature necessary to destroy lithium, and a lack of common processes to produce it.
Lithium is also found in brown dwarf stars and certain anomalous orange stars. Because lithium is present in cooler, less-massive brown dwarf stars, but is destroyed in hotter red dwarf stars, its presence in the stars' spectra can be used in the lithium test to differentiate the two, as both are smaller than the Sun. Certain orange stars can also contain a high concentration of lithium. Those orange stars found to have a higher than usual concentration of lithium orbit massive objects—neutron stars or black holes—whose gravity evidently pulls heavier lithium to the surface of a hydrogen-helium star, causing more lithium to be observed.
6.28.2010
Helium
Helium is the chemical element with atomic number 2, represented by the symbol He. The He is in 18º group and 1º period of periodic table and is a noble gas.
An unknown yellow spectral line signature in sunlight was first observed from a solar eclipse in 1868 by French astronomer Pierre Janssen. Janssen is jointly credited with the discovery of the element with Norman Lockyer, who observed the same eclipse and was the first to propose that the line was due to a new element which he named helium.
Helium is the second lightest element and is the second most abundant in the observable universe, being present in the universe in masses more than 12 times those of all the heavier elements combined. Its abundance is also similar to this in our own Sun and Jupiter. This is due to the very high binding energy (per nucleon) of helium-4 with respect to the next three elements after helium (lithium, beryllium, and boron). This helium-4 binding energy also accounts for its commonality as a product in both nuclear fusion and radioactive decay. Most helium in the universe is helium-4, and was formed during the Big Bang. Some new helium is being created presently as a result of the nuclear fusion of hydrogen in stars greater than 0.5 solar masses.
Helium is the next simplest atom to solve using the rules of quantum mechanics, after the hydrogen atom. Helium is composed of two electrons in orbit around a nucleus containing two protons along with some neutrons.
Helium is the least reactive noble gas after neon and thus the second least reactive of all elements; it is inert and monatomic in all standard conditions. Because of helium's relatively low molar (atomic) mass, its thermal conductivity, specific heat, and sound speed in the gas phase are all greater than any other gas except hydrogen. For similar reasons, and also due to the small size of helium atoms, helium's diffusion rate through solids is three times that of air and around 65% that of hydrogen.
Helium is less water soluble than any other gas known, and helium's index of refraction is closer to unity than that of any other gas. Helium has a negative Joule-Thomson coefficient at normal ambient temperatures, meaning it heats up when allowed to freely expand. Only below its Joule-Thomson inversion temperature (of about 32 to 50 K at 1 atmosphere) does it cool upon free expansion. Once precooled below this temperature, helium can be liquefied through expansion cooling.
Most extraterrestrial helium is found in a plasma state, with properties quite different from those of atomic helium. In a plasma, helium's electrons are not bound to its nucleus, resulting in very high electrical conductivity, even when the gas is only partially ionized. The charged particles are highly influenced by magnetic and electric fields.
Helium has a valence of zero and is chemically unreactive under all normal conditions. It is an electrical insulator unless ionized. Helium can form unstable compounds, known as excimers, with tungsten, iodine, fluorine, sulfur and phosphorus when it is subjected to an electric glow discharge, to electron bombardment, or else is a plasma for another reason. The molecular compounds HeNe, HgHe10, and WHe2, and the molecular ions He+2, He2+2, HeH+, and HeD+ have been created this way. This technique has also allowed the production of the neutral molecule He2, which has a large number of band systems, and HgHe, which is apparently only held together by polarization forces. Theoretically, other true compounds may also be possible, such as helium fluorohydride (HHeF) which would be analogous to HArF, discovered in 2000. Calculations show that two new compounds containing a helium-oxygen bond could be stable. Two new molecular species, predicted using theory, CsFHeO and N(CH3)4FHeO, are derivatives of a metastable [F– HeO] anion first theorized in 2005 by a group from Taiwan. If confirmed by experiment, such compounds will end helium's chemical inertness, and the only remaining inert element will be neon.
Helium has been put inside the hollow carbon cage molecules (the fullerenes) by heating under high pressure. The endohedral fullerene molecules formed are stable up to high temperatures. When chemical derivatives of these fullerenes are formed, the helium stays inside. If helium-3 is used, it can be readily observed by helium nuclear magnetic resonance spectroscopy. Many fullerenes containing helium-3 have been reported. Although the helium atoms are not attached by covalent or ionic bonds, these substances have distinct properties and a definite composition, like all stoichiometric chemical compounds. Helium was formed by Big Bang nucleosynthesis one to three minutes after the Big Bang. As such, measurements of its abundance contribute to cosmological models. In stars, it is formed by the nuclear fusion of hydrogen in proton-proton chain reactions and the CNO cycle, part of stellar nucleosynthesis.
6.25.2010
Hydrogen
Hydrogen, one of the most abundant elements of Universe. This element is found in great abundance in stars and gas giant planets. Molecular clouds of H2 are associated with star formation. Hydrogen plays a vital role in powering stars through proton-proton reaction and CNO cycle nuclear fusion.
Throughout the universe, hydrogen is mostly found in the atomic and plasma states whose properties are quite different from molecular hydrogen. As a plasma, hydrogen's electron and proton are not bound together, resulting in very high electrical conductivity and high emissivity (producing the light from the sun and other stars). The charged particles are highly influenced by magnetic and electric fields.
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an atomic weight of 1.00794 u (1.007825 u for Hydrogen-1), hydrogen is the lightest and most abundant chemical element, constituting roughly 75 % of the Universe's elemental mass.
The most common isotope of hydrogen is protium (name rarely used, symbol H) with a single proton and no neutrons. In ionic compounds it can take a negative charge (an anion known as a hydride and written as H−), or as a positively charged species H+. The latter cation is written as though composed of a bare proton, but in reality, hydrogen cations in ionic compounds always occur as more complex species. Hydrogen forms compounds with most elements and is present in water and most organic compounds. It plays a particularly important role in acid-base chemistry with many reactions exchanging protons between soluble molecules. As the simplest atom known, the hydrogen atom has been of theoretical use. For example, as the only neutral atom with an analytic solution to the Schrödinger equation, the study of the energetics and bonding of the hydrogen atom played a key role in the development of quantum mechanics.
Hydrogen gas (dihydrogen or molecular hydrogen) is highly flammable and will burn in air at a very wide range of concentrations between 4% and 75% by volume. The enthalpy of combustion for hydrogen is −286 kJ/mol:
2 H2(g) + O2(g) → 2 H2O(l) + 572 kJ (286 kJ/mol)
Hydrogen gas forms explosive mixtures with air in the concentration range 4–74% (volume per cent of hydrogen in air) and with chlorine in the range 5–95%. The mixtures spontaneously detonate by spark, heat or sunlight. The hydrogen autoignition temperature, the temperature of spontaneous ignition in air, is 500 °C (932 °F). Pure hydrogen-oxygen flames emit ultraviolet light and are nearly invisible to the naked eye, as illustrated by the faint plume of the Space Shuttle main engine compared to the highly visible plume of a Space Shuttle Solid Rocket Booster. The detection of a burning hydrogen leak may require a flame detector; such leaks can be very dangerous.
The ground state energy level of the electron in a hydrogen atom is −13.6 eV, which is equivalent to an ultraviolet photon of roughly 92 nm wavelength.
Hydrogen has three naturally occurring isotopes, denoted 1H, 2H and 3H. Other, highly unstable nuclei (4H to 7H) have been synthesized in the laboratory but not observed in nature.
1H is the most common hydrogen isotope with an abundance of more than 99.98%. Because the nucleus of this isotope consists of only a single proton, it is given the descriptive but rarely used formal name protium.
2H, the other stable hydrogen isotope, is known as deuterium and contains one proton and one neutron in its nucleus. Essentially all deuterium in the universe is thought to have been produced at the time of the Big Bang, and has endured since that time. Deuterium is not radioactive, and does not represent a significant toxicity hazard. Water enriched in molecules that include deuterium instead of normal hydrogen is called heavy water. Deuterium and its compounds are used as a non-radioactive label in chemical experiments and in solvents for 1H-NMR spectroscopy. Heavy water is used as a neutron moderator and coolant for nuclear reactors. Deuterium is also a potential fuel for commercial nuclear fusion.
3H is known as tritium and contains one proton and two neutrons in its nucleus. It is radioactive, decaying into helium-3 through beta decay with a half-life of 12.32 years. Small amounts of tritium occur naturally because of the interaction of cosmic rays with atmospheric gases; tritium has also been released during nuclear weapons tests. It is used in nuclear fusion reactions, as a tracer in isotope geochemistry, and specialized in self-powered lighting devices. Tritium has also been used in chemical and biological labeling experiments as a radiolabel. Hydrogen is the only element that has different names for its isotopes in common use today.
Because of its relatively simple atomic structure, consisting only of a proton and an electron, the hydrogen atom, together with the spectrum of light produced from it or absorbed by it, has been central to the development of the theory of atomic structure. Furthermore, the corresponding simplicity of the hydrogen molecule and the corresponding cation H2+ allowed fuller understanding of the nature of the chemical bond, which followed shortly after the quantum mechanical treatment of the hydrogen atom had been developed in the mid-1920s.
One of the first quantum effects to be explicitly noticed (but not understood at the time) was a Maxwell observation involving hydrogen, half a century before full quantum mechanical theory arrived. Maxwell observed that the specific heat capacity of H2 unaccountably departs from that of a diatomic gas below room temperature and begins to increasingly resemble that of a monatomic gas at cryogenic temperatures. According to quantum theory, this behavior arises from the spacing of the (quantized) rotational energy levels, which are particularly wide-spaced in H2 because of its low mass. These widely spaced levels inhibit equal partition of heat energy into rotational motion in hydrogen at low temperatures. Diatomic gases composed of heavier atoms do not have such widely spaced levels and do not exhibit the same effect.
Etiquetas:
abundance,
atom,
galaxy,
hydrogen,
periodic table,
primordial,
star,
sun,
Universe
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