Neptune is the eighth and farthest planet from the Sun in our Solar System. Discovered on September 23, 1846, Neptune was the first planet found by mathematical prediction rather than by empirical observation. Unexpected changes in the orbit of Uranus led Alexis Bouvard to deduce that its orbit was subject to gravitational perturbation by an unknown planet. Neptune was subsequently observed by Johann Galle within a degree of the position predicted by Urbain Le Verrier, and its largest moon, Triton, was discovered shortly thereafter, though none of the planet's remaining 12 moons were located telescopically until the 20th century. Neptune has been visited by only one spacecraft, Voyager 2, which flew by the planet on August 25, 1989.
From its discovery until 1930, Neptune was the farthest known planet. Upon the discovery of Pluto in 1930, Neptune became the penultimate planet, save for a 20-year period between 1979 and 1999 when Pluto fell within its orbit. However, the discovery of the Kuiper belt in 1992 led many astronomers to debate whether Pluto should be considered a planet in its own right or part of the belt's larger structure. In 2006, the International Astronomical Union defined the word "planet" for the first time, reclassifying Pluto as a "dwarf planet" and making Neptune once again the last planet in the Solar System.
Neptune's internal structure resembles that of Uranus. Its atmosphere forms about 5 to 10 percent of its mass and extends perhaps 10 to 20 percent of the way towards the core, where it reaches pressures of about 10 GPa. Increasing concentrations of methane, ammonia and water are found in the lower regions of the atmosphere.
Gradually this darker and hotter region condenses into a superheated liquid mantle, where temperatures reach 2,000 K to 5,000 K. The mantle is equivalent to 10 to 15 Earth masses and is rich in water, ammonia and methane. As is customary in planetary science, this mixture is referred to as icy even though it is a hot, highly dense fluid. This fluid, which has a high electrical conductivity, is sometimes called a water-ammonia ocean. At a depth of 7000 km, the conditions may be such that methane decomposes into diamond crystals that then precipitate toward the core.
The core of Neptune is composed of iron, nickel and silicates, with an interior model giving a mass about 1.2 times that of the Earth. The pressure at the centre is 7 Mbar (700 GPa), millions of times more than that on the surface of the Earth, and the temperature may be 5,400 K.
At high altitudes, Neptune's atmosphere is 80% hydrogen and 19% helium. A trace amount of methane is also present. Prominent absorption bands of methane occur at wavelengths above 600 nm, in the red and infrared portion of the spectrum. As with Uranus, this absorption of red light by the atmospheric methane is part of what gives Neptune its blue hue, although Neptune's vivid azure differs from Uranus's milder aquamarine. Since Neptune's atmospheric methane content is similar to that of Uranus, some unknown atmospheric constituent is thought to contribute to Neptune's colour.
Neptune's atmosphere is sub-divided into two main regions; the lower troposphere, where temperature decreases with altitude, and the stratosphere, where temperature increases with altitude. The boundary between the two, the tropopause, occurs at a pressure of 0.1 bars (10 kPa). The stratosphere then gives way to the thermosphere at a pressure lower than 10−5 to 10−4 microbars (1 to 10 Pa).
The thermosphere gradually transitions to the exosphere. Models suggest that Neptune's troposphere is banded by clouds of varying compositions depending on altitude. The upper-level clouds occur at pressures below one bar, where the temperature is suitable for methane to condense. For pressures between one and five bars (100 and 500 kPa), clouds of ammonia and hydrogen sulfide are believed to form. Above a pressure of five bars, the clouds may consist of ammonia, ammonium sulfide, hydrogen sulfide and water. Deeper clouds of water ice should be found at pressures of about 50 bars (5.0 MPa), where the temperature reaches 0 °C. Underneath, clouds of ammonia and hydrogen sulfide may be found.
High-altitude clouds on Neptune have been observed casting shadows on the opaque cloud deck below. There are also high-altitude cloud bands that wrap around the planet at constant latitude. These circumferential bands have widths of 50–150 km and lie about 50–110 km above the cloud deck.
Neptune's spectra suggest that its lower stratosphere is hazy due to condensation of products of ultraviolet photolysis of methane, such as ethane and acetylene. The stratosphere is also home to trace amounts of carbon monoxide and hydrogen cyanide.The stratosphere of Neptune is warmer than that of Uranus due to the elevated concentration of hydrocarbons.
For reasons that remain obscure, the planet's thermosphere is at an anomalously high temperature of about 750 K. The planet is too far from the Sun for this heat to be generated by ultraviolet radiation. One candidate for a heating mechanism is atmospheric interaction with ions in the planet's magnetic field. Other candidates are gravity waves from the interior that dissipate in the atmosphere. The thermosphere contains traces of carbon dioxide and water, which may have been deposited from external sources such as meteorites and dust.
Neptune also resembles Uranus in its magnetosphere, with a magnetic field strongly tilted relative to its rotational axis at 47° and offset at least 0.55 radii, or about 13500 km from the planet's physical centre. Before Voyager 2's arrival at Neptune, it was hypothesised that Uranus's tilted magnetosphere was the result of its sideways rotation. However, in comparing the magnetic fields of the two planets, scientists now think the extreme orientation may be characteristic of flows in the planets' interiors. This field may be generated by convective fluid motions in a thin spherical shell of electrically conducting liquids (probably a combination of ammonia, methane and water) resulting in a dynamo action.
The dipole component of the magnetic field at the magnetic equator of Neptune is about 14 microteslas (0.14 G). The dipole magnetic moment of Neptune is about 2.2 × 1017 T·m3 (14 μT·RN3, where RN is the radius of Neptune). Neptune's magnetic field has a complex geometry that includes relatively large contributions from non-dipolar components, including a strong quadrupole moment that may exceed the dipole moment in strength. By contrast, Earth, Jupiter and Saturn have only relatively small quadrupole moments, and their fields are less tilted from the polar axis. The large quadrupole moment of Neptune may be the result of offset from the planet's center and geometrical constraints of the field's dynamo generator.
Neptune's bow shock, where the magnetosphere begins to slow the solar wind, occurs at a distance of 34.9 times the radius of the planet. The magnetopause, where the pressure of the magnetosphere counterbalances the solar wind, lies at a distance of 23–26.5 times the radius of Neptune. The tail of the magnetosphere extends out to at least 72 times the radius of Neptune, and very likely much farther.
Neptune has a planetary ring system, though one much less substantial than that of Saturn. The rings may consist of ice particles coated with silicates or carbon-based material, which most likely gives them a reddish hue. The three main rings are the narrow Adams Ring, 63000 km from the centre of Neptune, the Le Verrier Ring, at 53000 km, and the broader, fainter Galle Ring, at 42000 km. A faint outward extension to the Le Verrier Ring has been named Lassell; it is bounded at its outer edge by the Arago Ring at 57000 km.
One difference between Neptune and Uranus is the typical level of meteorological activity. When the Voyager 2 spacecraft flew by Uranus in 1986, that planet was visually quite bland. In contrast Neptune exhibited notable weather phenomena during the 1989 Voyager 2 fly-by.
In 1989, the Great Dark Spot, an anti-cyclonic storm system spanning 13000×6600 km, was discovered by NASA's Voyager 2 spacecraft. The storm resembled the Great Red Spot of Jupiter. Some five years later, however, on November 2, 1994, the Hubble Space Telescope did not see the Great Dark Spot on the planet. Instead, a new storm similar to the Great Dark Spot was found in the planet's northern hemisphere.
The Scooter is another storm, a white cloud group farther south than the Great Dark Spot. Its nickname is due to the fact that when first detected in the months before the 1989 Voyager 2 encounter it moved faster than the Great Dark Spot. Subsequent images revealed even faster clouds. The Small Dark Spot is a southern cyclonic storm, the second-most-intense storm observed during the 1989 encounter. It initially was completely dark, but as Voyager 2 approached the planet, a bright core developed and can be seen in most of the highest-resolution images.
Neptune's dark spots are thought to occur in the troposphere at lower altitudes than the brighter cloud features, so they appear as holes in the upper cloud decks. As they are stable features that can persist for several months, they are thought to be vortex structures. Often associated with dark spots are brighter, persistent methane clouds that form around the tropopause layer. The persistence of companion clouds shows that some former dark spots may continue to exist as cyclones even though they are no longer visible as a dark feature. Dark spots may dissipate when they migrate too close to the equator or possibly through some other unknown mechanism.
Neptune's more varied weather when compared to Uranus is believed to be due in part to its higher internal heat. Although Neptune lies half again as far from the Sun as Uranus, and receives only 40% its amount of sunlight, the two planets' surface temperatures are roughly equal. The upper regions of Neptune's troposphere reach a low temperature of −221.4 °C (51.7 K).
The average distance between Neptune and the Sun is 4.55 billion km (about 30.1 AU), and it completes an orbit every 164.79 years. On July 12, 2011, Neptune will have completed the first full orbit since its discovery in 1846, although it will not appear at its exact discovery position in our sky because the Earth will be in a different location in its 365.25-day orbit.
The elliptical orbit of Neptune is inclined 1.77° compared to the Earth. Because of an eccentricity of 0.011, the distance between Neptune and the Sun varies by 101 million km between perihelion and aphelion, the nearest and most distant points of the planet from the Sun along the orbital path, respectively.
The axial tilt of Neptune is 28.32°, which is similar to the tilts of Earth (23°) and Mars (25°). As a result, this planet experiences similar seasonal changes. However, the long orbital period of Neptune means that the seasons last for forty Earth years. Its sidereal rotation period (day) is roughly 16.11 hours. Since its axial tilt is comparable to the Earth's, the variation in the length of its day over the course of its long year is not any more extreme.
Because Neptune is not a solid body, its atmosphere undergoes differential rotation. The wide equatorial zone rotates with a period of about 18 hours, which is slower than the 16.1-hour rotation of the planet's magnetic field. By contrast, the reverse is true for the polar regions where the rotation period is 12 hours. This differential rotation is the most pronounced of any planet in the Solar System, and it results in strong latitudinal wind shear.
Neptune has 13 known moons. The largest by far, comprising more than 99.5 percent of the mass in orbit around Neptune and the only one massive enough to be spheroidal, is Triton, discovered by William Lassell just 17 days after the discovery of Neptune itself. Unlike all other large planetary moons in the Solar System, Triton has a retrograde orbit, indicating that it was captured rather than forming in place; it probably was once a dwarf planet in the Kuiper belt. It is close enough to Neptune to be locked into a synchronous rotation, and it is slowly spiraling inward because of tidal acceleration and eventually will be torn apart, in about 3.6 billion years, when it reaches the Roche limit. In 1989, Triton was the coldest object that had yet been measured in the solar system, with estimated temperatures of −235 °C (38 K).
Neptune's second known satellite (by order of discovery), the irregular moon Nereid, has one of the most eccentric orbits of any satellite in the solar system. The eccentricity of 0.7512 gives it an apoapsis that is seven times its periapsis distance from Neptune.
From July to September 1989, Voyager 2 discovered six new Neptunian moons. Of these, the irregularly shaped Proteus is notable for being as large as a body of its density can be without being pulled into a spherical shape by its own gravity. Although the second-most-massive Neptunian moon, it is only one-quarter of one percent the mass of Triton. Neptune's innermost four moons—Naiad, Thalassa, Despina and Galatea—orbit close enough to be within Neptune's rings. The next-farthest out, Larissa was originally discovered in 1981 when it had occulted a star. This occultation had been attributed to ring arcs, but when Voyager 2 observed Neptune in 1989, it was found to have been caused by the moon. Five new irregular moons discovered between 2002 and 2003 were announced in 2004.
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